Recall a version of separation theorem for a Banach space is the following.
Theorem 1. Let X be a Banach space. Let C be a nonempty open convex subset of X and x_0 \in X \backslash C. Then there exists \ell_0 \in X^* such that \sup_{x \in C} \Re \ell_0(x) < \Re \ell_0(x_0).
There is a separation theorem in the weak* topology setting.
Theorem 2. Let X be a Banach space. Let C be a nonempty weak*-closed convex subset of X^* and \ell_0 \in X^* \backslash C. Then there exists x_0 \in X such that \sup_{\ell \in C} \Re \ell(x_0) < \Re \ell_0(x_0).
Proof: Since X^* \backslash C is weak*-open, we can find x_1, \ldots, x_n \in X and \epsilon > 0 such that U = \{\ell \in X^* : |\ell(x_i)| < \epsilon, i = 1, \ldots, n\} satisfies \ell_0 + U \subset X^* \backslash C. This implies that \ell_0 does not lie in the convex open set C + U. By Theorem 1 there exists \psi \in X^{**} such that \Re \psi(\ell_0) > \sup_{\ell \in C + U} \Re \psi(\ell) \geq \sup_{\ell \in C} \Re \psi(\ell). We want to show that \cap_{i = 1}^n \ker(x_i) \subseteq \ker(\psi), since then \psi is a linear combination of x_1, \ldots, x_n, thus x_0 = \psi \in X and we are done. Let \ell \in X^* with \ell(x_i) for all 1 \leq i \leq n. Note that t\ell \in U for all t \in \mathbb{R}. Fix any c \in C. Then M := \sup_{f \in U} \psi(f) < \psi(\ell_0) - \psi(c) is finite. Now for all t \in \mathbb{R}, \psi(t\ell) \leq M, i.e. \psi(\ell) \leq M/t for all t > 0 and \psi(\ell) \geq M/t for all t < 0. Therefore \psi(\ell) = 0.
The following is an application of the weak* separation theorem. (Notation: B_Y = \{y \in Y: \|y\| \leq 1\}.)
Theorem (Goldstine). The weak* closure of B_X in X^{**} is B_{X^{**}}.
Proof: First, B_X \subseteq B_{X^{**}} and B_{X^{**}} is weak*-compact by Alaoglu's Theorem. Hence the weak* closure \tilde{B} of B_X is a subset of B_{X^{**}}. Suppose the inclusion is proper and choose w \in B_{X^{**}} \backslash \tilde{B}. Apply Theorem 2 to find an \ell \in X^* and \epsilon > 0 such that \sup_{\psi \in \tilde{B}} \Re \psi(\ell_0) \leq \Re w(\ell_0) - \epsilon. In particular, \Re \ell_0(x) \leq \Re w(\ell_0) - \epsilon for all x \in B_X. This implies that |\ell_0(x)| \leq \Re w(\ell_0) - \epsilon for all x \in B_X. Replace w by some e^{-i\theta}w, we have |\ell_0(x)| \leq |w(\ell_0)| - \epsilon for all x \in B_X. But then \|\ell_0\| \leq |w(\ell_0)| - \epsilon \leq \|w\|\|\ell_0\| - \epsilon = \|\ell_0\| - \epsilon. This is a contradiction.
Reference:
Fabian, Habala, Hajek, Santalucia, Pelant, Zizler - Functional Analysis and Infinite Dimensional Geometry
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